Luminescent Solar Concentrators
Luminescent Solar Concentrators (LSCs) are a versatile device that shows potential for a simple and diverse solution for aesthetically pleasing photovoltaic integration. The device is comprised of polymer sheets, doped with fluorophores such a fluorescent dye, quantum dots or rare earth materials. Incident light is absorbed by the fluorophores and reemitted at a longer wavelength. Some of this reemitted light is then trapped within the polymer, and wave guided towards the edges, where it is collected at the edges by attached photovoltaic panels.
Applications range from large scale; Building Integrated Photovoltaics (BIPV) such as windows, walls or roadside barriers, mid-scale; such as window blinds, tent or boat sails, through to small scale applications such as wearable technologies, watch straps or furniture.
We have explored the fundamental limits in performance of LSCs (Papakonstantinou and Tummeltshammer, 2015), alignment of fluorophores and energy transfer (Tummeltshammer et al., 2014, 2016), to pursue a better understanding of the possibilities for highly-efficient LSCs.
The group has developed a Monte-Carlo Raytracing model allowing for accurate and efficient modelling of the device. Simulation allows for easy optimisation of devices saving resources and time, as well as exploring possibilities for the technologies expansion. The model outputs the devices efficiency as well as showing expected losses. This has been further combined with FDTD to create a hybrid model that can model from nano to macro scale devices, allowing us to explore the use of plasmonic LSCs (Tummeltshammer et al., 2013).
Tummeltshammer, C., Brown, M. S., Taylor, A., Kenyon, A. J. and Papakonstantinou, I. (2013) ‘Efficiency and loss mechanisms of plasmonic Luminescent Solar Concentrators’, Optics Express, 21(S5), p. A735. doi: 10.1364/OE.21.00A735.
Tummeltshammer, C., Taylor, A., Kenyon, a J. and Papakonstantinou, I. (2014) ‘Homeotropic alignment and FRET : the way to a brighter luminescent solar concentrator’, Journal of Applied Physics, 173103, pp. 1–7. doi: 10.1063/1.4900986.
Papakonstantinou, I. and Tummeltshammer, C. (2015) ‘Fundamental limits of concentration in luminescent solar concentrators revised: the effect of reabsorption and nonunity quantum yield’, Optica. Optical Society of America, 2(10), p. 841. doi: 10.1364/OPTICA.2.000841.
Tummeltshammer, C., Taylor, A., Kenyon, A. J. and Papakonstantinou, I. (2016) ‘Losses in luminescent solar concentrators unveiled’, Solar Energy Materials and Solar Cells. Elsevier, 144, pp. 40–47. doi: 10.1016/j.solmat.2015.08.008.
Tummeltshammer, C., Taylor, A., Kenyon, A. J. and Papakonstantinou, I. (2016) ‘Flexible and fluorophore-doped luminescent solar concentrators based on polydimethylsiloxane’, Optics Letters, 41(4), pp. 713–716.
Tummeltshammer, C., Portnoi, M., Mitchell, S. A., Lee, A.-T., Kenyon, A. J., Tabor, A. B. and Papakonstantinou, I. (2016) ‘On the Ability of Förster Resonance Energy Transfer to Enhance Luminescent Solar Concentrator Efficiency’, Nano Energy. Elsevier, 32, pp. 263–270. doi: 10.1016/j.nanoen.2016.11.058.
SupportEPSRC Doctoral Training Award